Chloride stress corrosion cracking in austenitic stainless. For a given alloy, the testing result depends on the stress state and environment. The material used in the present study is 304 stainless steel, the chemical composition of it is shown in table i. Current density and applied load were monitored during corrosion tests. For example, boiling 42% mgcl2 solution is widely used as a test for the susceptibility of austenitic stainless steels to chloride stress corrosion cracking, and this test may be used to rank alloys or to check components for the presence of residual stresses. This makes these plants susceptible to chlorideinduced stress corrosion cracking cscc. The tensile stress may be residual stress resulting from heat treatment. Stress corrosion cracking scc is difficult to predict and identify, and it can lead to catastrophic failure, often without any prior warning. Chlorideinduced stresscorrosion cracking scc is one of the failure modes of stainless steels.
A great concern for the longterm integrity of canisters located near the coastline is chlorideinduced stress corrosion cracking of austenitic stainless steels 3,4,5. The boiling magnesium chloride test cracks materials with the nickel levels. Assessment of susceptibility to chloride stress corrosion. Product test report ptr4183 swagelok company ver 02 29500 solon road november 2018 solon, ohio 449 u. The impact of scc on a material usually falls between dry cracking and the fatigue threshold of that material. Corrosion tests professional testing services test.
Cscc can attack highly resistant austenitic stainless steel. Deterioration by clscc can lead to failures that have the potential to release stored energy andor hazardous substances. Chlorideinduced stress corrosion cracking of powder. Astm g36 evaluating scc resistance of metals and alloys in boiling magnesium chloride. Considering the effects of chloride contamination on corrosion and cracking, the chloride limit in fge has been reduced from 40 ppm to 10 ppm in the latest version of astm d4806, which is the spec controlling fge. Aluminum alloys that contain appreciable amounts of soluble alloying elements, primarily copper, magnesium, silicon, and zinc, are susceptible to stresscorrosion cracking scc. Dunn nrcnmsssfst public meetingggy with nuclear energy institute on chloride induced stress corrosion cracking regulatory issue resolution protocol august 5, 2014. Monitoring of chloride stress corrosion cracking of austenitic. Highly alloyed austenitic stainless steels s32654, s31254, and n08028, and duplex grades s32750 and s31803 possess much improved resistance to scc compared with s30400 and s31600 steels. Chloride stress corrosion is a type of intergranular corrosion and occurs in austenitic stainless steel under tensile stress in the presence of.
This practice describes a procedure for conducting stresscorrosion cracking tests in a boiling magnesium chloride solution. However, no data were found that could be used to predict the time required for crack initiation by localised corrosion in real structures. This article describes the susceptibility of 316l stainless steel to stress corrosion cracking scc in a nitritecontaining chloride solution. This test method is performed in 25 % by mass sodium chloride acidified to ph 1.
Ctlastm g36 stress corrosion cracking in a boiling. Atmospheric salt fog testing to evaluate chloride induced stress corrosion cracking of type 304, 304l, and 316l stainless steel todd s. Developing field test procedures for chloride stress. Chloride stress corrosion cracking in austenitic stainless steel, assessing susceptibility and structural integrity, uk, prepared by the health and safety laboratory for the health and safety executive, 2011 r parrott, et. Nace tm0284 hydrogen induced cracking hic astm standard tests, including. Polarization curves on titanium oxide surfaces and kinetic data for oxidation of newly formed titanium alloy surface were also obtained. The required tensile stresses may be in the form of directly applied stresses or in the form of residual. The diagram indicates the temperaturechloride range within which sandvik saf 2205 and the standard steels astm 304l and astm 316l can be used without risk of stress corrosion cracking. Tests for stresscorrosion stresscorrosion cracking is a timedependent process in which a metallurgically susceptible material fractures prematurely due to the synergistic interaction of a corrosive environment and sustained tensile stress at the metal surface.
An investigation was carried out on the effect of stress, chloride concentration, temperature and oxygen on the stress corrosion cracking behaviour of 188 and 18 mo steels. The range of instruments available to perform these tests is unrivaled in across geographies. Stress corrosion cracking susceptibility of 304l substrate. In combination with corrosive environments, stress corrosion cracks can form in a wide variety of industrial metals and materials. Stress corrosion cracking scc is the cracking induced from the combined influence of tensile stress and a corrosive environment. Astm g 48 stainless steel pitting and crevice corrosion in. Tcr engineering mumbai corrosion testing, nace, astm. It can be detrimental to austenitic stainless steels, one of the main reasons these steels are not considered a cureall for corrosion problems.
Astm g36 stress corrosion cracking in a boiling magnesium chloride solution. Pdf stress corrosion cracking of austenitic stainless. This phenomenon is generally termed sulfide stress cracking ssc when operating at room temperature and stress corrosion cracking scc when operating at higher temperatures. Although this test may be performed using various concentrations of magnesium chloride, this procedure covers a test solution held at a constant boiling temperature of 155. Stress corrosion cracking of an austenitic stainless steel. Stress corrosion cracking of titanium preliminary report. Mintz1, leonardo caseres2, darrell s dunndarrell s. Drop evaporation test method, author steinsmo, u and drugli, j m, abstractnote stress corrosion cracking scc of chloride exposed stainless steels under evaporative conditions has for long been recognized as a factor that needed special attention. Chlorideinduced stress corrosion cracking tests and. Astm g123 evaluating scc of stainless alloys with different nickel. Chlorideoxygen stress corrosion cracking mechanisms of austenitic chromiumnickel steels in high purity water at 250 to 350 c over a wide range of stress levels is reported. Astm g123 002015 standard test method for evaluating stress. Chloride contamination might also be possible from aerosolized chloride for storage tanks located close to the ocean. Results of laboratory tests carried out in calcium chloride are shown in figure 8.
Chloride stress corrosion cracking is a well known form of scc, typically caused by inadvertently contaminating equipment with chlorides. Corrosion under insulation cui is a severe problem for 304 stainless steel pressure vessel. Elements scc capabilities help to quickly evaluate the susceptibility of metallic materials to cracking and determine the size and scope of the problem before the failure occurs, avoiding major. A wide variety of corrosion related tests can be undertaken at tcr engineering services to determine weight loss corrosion, intergranular corrosion attack, pitting corrosion, corrosion fatigue, stress corrosion cracking, sulfide stress corrosion cracking, and hydrogeninduced corrosion cracking. Tests for stresscorrosion stress corrosion cracking is a timedependent process in which a metallurgically susceptible material fractures prematurely due to the synergistic interaction of a corrosive environment and sustained tensile stress at the metal surface. The stress corrosion cracking scc and hydrogen embrittlement he behaviors for types 304, 310, and 316 austenitic stainless steels were investigated in boiling saturated magnesium chloride solutions using a constant load method under different conditions including test temperature, applied stress, and sensitization. The relative resistance of a stainless steel to chloride scc is often quantified by the use of standard boiling salt solutions. The mechanism of chloride stress corrosion cracking clscc is complex and the current understanding is discussed in section 5 of this report. Astm g123 002015 standard test method for evaluating. Chloride stress corrosion cracking clscc is one the most common reasons why austenitic stainless steel pipework and vessels deteriorate in the chemical processing and petrochemical industries. Chloride stress corrosion cracking inspectioneering. The chlorideinduced stress corrosion cracking scc resistance of nitrogenalloyed, powder metallurgically pm produced and hot isostatically pressed hip duplex stainless steels dss was investigated and compared to the scc resistance of two commercial wrought forged dss. This study is to identify factors responsible for loss of production due to problems in plant and equipment. Oil and gas production and petrochemical plants in the arabian gulf are exposed to severe environmental conditions of high temperature and humidity.
Laboratory tests duplicated plant experience and demonstrated that type304 stainless steel which was sensitized and pickled in the commonly used hnosub 3. Structural failure due to scc can be very unpredictablefailure could occur after as little as a few hours of exposure, or the equipment could continue to function normally for. Corrosionpedia what is stress corrosion cracking scc. Novel chloride stress corrosion cracking test was validated by acoustic emission.
The chloride stresscorrosion cracking behavior of stainless steels. Astm g103 scc test of alznmg alloys in boiling 6% sodium chloride solutions. A cost efficient field test setup for cscc was designed and developed for. Hf acid is extremely susceptible to stress corrosion cracking in water with a very low concentration of chloride ion. Materials free fulltext stress corrosion cracking of. The decay heat of the spent nuclear fuel in dry storage, by design, will dissipate through. Stresscorrosion cracking ex periments can be categorized as. The combined action of tensile stress with corrosive environment can lead to chloride stress corrosion cracking cscc.
Influence of high temperature on corrosion behavior of 304. Tests on statically loaded smooth samples tests on statically loaded precracked sam ples tests using slowly straining samples more detailed information on these tests can be found in the chapter evaluation of stresscorrosion cracking and in ref 8. With the development of a database, ssdata, experimental data collected from calcium chloride tests. Elements stress corrosion cracking scc testing evaluates the susceptibility of metals to cracking failure under tensile stress and corrosion. One of the most important forms of stress corrosion that concerns the nuclear industry is chloride stress corrosion. This test method is concerned primarily with the test solution and glassware, although a specific style. Presented in this report are the results of stress corrosion cracking testing per astm g36 standard practice for performing stresscorrosion cracking tests in a boiling magnesium chloride solution of welded bare and finned tubes fabricated from steel. Chloride stress corrosion cracking in austenitic stainless steel. The test method covers procedures for the determination of the resistance of stainless steels and related alloys to pitting and crevice corrosion when exposed to oxidizing chloride environments. An extensive failure analysis shows how many service failures occurred in the industry and what kind of alloys and stresses led to initiation and propagation of stress corrosion cracks which caused these service failures. Addition of nitrite to the chloride solution, which is reported to have inhibitive influence on corrosion of stainless. Stress corrosion cracking international institute of. Developing field test procedures for chloride stress corrosion. Controlling chloride stress corrosion cracking the main options for preventing or controlling chloride stress corrosion cracking clscc are management of chloride levels, temperature, and ph.
Chloride stress corrosion cracking is a localized corrosion mechanism like pitting and crevice corrosion. Essentially clscc involves a combination of the electrochemistry of metal dissolving over a highly localised area, i. Standard test method for evaluating stresscorrosion cracking of stainless alloys. The effects of prior cold work cw and sensitization treatment on the stress corrosion cracking scc behaviour of type 304 stainless steels have been studied in chloride solutions using electrochemical tests and magnesium chloride tests with ubend specimen.
Chloride stress corrosion cracking clscc is a type of stress corrosion cracking scc and is one of the most well known forms of scc in the refining and chemical processing industries. Laboratory stress corrosion cracking tests offered by g2mt labs include. Stress corrosion cracking scc is a progressive fracturing that occurs in metals as a result of the combined influence of tensile stress and a corrosive environment. Inhibitors can also be effective where the process allows it. Chlorideinduced stress corrosion cracking tests and example aging management program darrell s. Stress corrosion cracking can lead to catastrophic brittle failure.
Clscc chloride stress corrosion cracking mechanism china. The laboratory testing fails to provide the exact field environmental conditions. The laboratory testing fails to provide the exact field. It requires a susceptible material and, depending on the material, sufficient levels of. Standard practice for evaluating stresscorrosioncracking. Stress corrosion cracking scc can occur in a most metals and alloys due to the combined action of corrosion, tensile stress residual or applied and a susceptible microstructure. A wide variety of corrosion related tests is undertaken at tcr advanced to determine the susceptibility to intergranular corrosion, pitting corrosion, stress corrosion cracking, etc. Both of type 304 and type 316 stainless steels showed quite similar. The test addresses the resistance of metals to cracking failure under the combined action of tensile stress and corrosion in aqueous environments conatining hydrogen sulfide h 2 s. Chloride induced stress corrosion cracking tests and example aging management program darrell s.
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